International Journal of Marine Science, 2017, Vol.7, No.22, 205-213
209
Continued Table 2
Depths
(cm)
Metals
Sn
Be
Sc
S (%) Y
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho
Er
0-2
0.5
<1
3.5
<0.04 8.4
18.25 2.1
9.5
1.8
0.4
2.0
0.2
1.5
0.3
0.7
2-4
0.4
<1
3.7
<0.04 8.5
17.78 2.4
8.5
2.0
0.5
1.4
0.2
1.5
0.3
0.8
4-6
0.6
<1
3.4
<0.04 8.1
15.97 2.0
8.5
1.7
0.4
1.4
0.2
1.5
0.3
0.8
6-8
0.5
<1
3.3
<0.04 8.2
16.54 2.2
8.3
1.8
0.5
1.4
0.2
1.4
0.3
0.8
8-10
0.5
<1
3.4
<0.04 8.3
16.27 2.2
8.3
1.7
0.4
1.7
0.2
1.5
0.3
0.8
Depths
(cm)
Metals
Tm
Yb
Lu
Hf
Li
Rb
Ta
Nb
Cs
Ga
In
Re
Se
Te
Tl
0-2
0.1
0.7
0.1
0.63
14.7 22.0
<0.1 1.65 0.7
3.27 0.03
<0.002 <0.3 0.31 0.10
2-4
<0.1 0.6
<0.1 0.51
14.0 22.3
0.1
1.72 0.7
3.36 <0.01 <0.002 <0.3 0.25 0.10
4-6
0.1
0.7
<0.1 0.48
14.8 22.5
<0.1 1.48 0.7
3.07 <0.01 <0.002 <0.3 0.31 0.11
6-8
0.1
0.7
0.1
0.57
14.3 22.1
<0.1 1.56 0.7
3.21 0.02
<0.002 <0.3 0.43 0.11
8-10
<0.1 0.7
<0.1 0.56
14.4 23.4
<0.1 1.65 0.7
3.03 0.01
<0.002 <0.3 0.33 0.11
Table 3 Mean concentrations (ppm) of metals in sediments of Inner Harbor of Sinop Peninsula in the Black Sea
Depths
(cm)
Metals
Mo Cu
Pb
Zn
Ag
Ni
Co Mn
Fe(%) As
U
Au
Th
Sr
Cd
Hg
0-2
0.27 14.44 14.45 34.9
58
16.5 9.0 460
2.37
7.8
0.8
<0.1
2.6
525 0.05 <0.01
2-4
1.00 12.54 13.61 31.6
51
15.9 8.2 449
1.99
5.5
0.6
<0.1
2.0
595 0.05 0.02
4-6
0.21 16.31 13.12 31.6
65
14.1 7.5 421
1.74
4.9
0.7
<0.1
2.1
737 0.06 0.02
6-8
0.22 17.13 15.70 29.2
60
14.7 5.3 328
1.43
5.9
0.7
<0.1
2.3
906 0.09 0.01
8-10
0.24 12.78 13.50 26.4
88
13.1 5.3 790
1.43
7.2
1.0
<0.1
4.3
823 0.07 0.02
Depths
(cm)
Metals
Sb
Bi
V
Ca(%) P (%) La
Cr Mg(%) Ba
Ti(%) Al(%) Na (%) K(%) W
Zr
0-2
0.39 0.05 111
14.05 0.039 10.3 148 1.17
107
0.251 2.13
0.745 0.52 0.5 36.5
2-4
0.30 0.04 90
15.79 0.039 9.6
141 1.21
128
0.208 2.15
0.796 0.58 0.3 29.0
4-6
0.33 0.04 74
21.43 0.039 9.3
81 1.04
123
0.176 1.96
0.794 0.51 0.4 27.2
6-8
0.38 0.09 51
23.87 0.042 9.2
52 0.88
142
0.137 1.78
0.761 0.57 0.4 24.9
8-10
0.64 0.04 45
23.72 0.037 11.0 43 0.96
136
0.124 2.21
0.765 0.71 0.6 33.6
Depths
(cm)
Metals
Sn
Be
Sc
S (%) Y
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy
Ho Er
0-2
3.2
<1
17.8 <0.04 9.2
20.43 2.7 11.5
3.0
0.7
2.3
0.3
1.8
0.3 0.8
2-4
2.5
<1
17.2 <0.04 9.3
20.44 2.7 11.5
2.6
0.6
2.3
0.3
1.7
0.3 0.8
4-6
2.7
<1
14.9 0.05
8.8
18.82 2.3 10.4
2.2
0.5
1.9
0.3
1.8
0.3 0.9
6-8
1.5
<1
11.0 0.05
7.1
18.37 2.2 8.5
2.0
0.4
1.5
0.2
1.6
0.3 0.9
8-10
1.2
<1
11.7 0.07
10.7 20.61 2.8 10.3
2.9
0.5
2.1
0.4
1.9
0.3 1.1
Depths
(cm)
Metals
Tm Yb
Lu
Hf
Li
Rb
Ta Nb
Cs
Ga
In
Re
Se
Te
Tl
0-2
0.2
0.8
0.1
1.14
9.3
16.5 0.2 2.84
0.6
4.98 0.02
<0.002 <0.3 0.55 0.09
2-4
0.1
1.0
0.1
0.81
7.5
17.1 0.1 2.20
0.5
4.51 0.03
<0.002 <0.3 1.82 0.07
4-6
<0.1 0.9
0.1
0.91
10.0 18.3 0.1 2.11
0.5
4.40 <0.01 <0.002 <0.3 0.41 0.09
6-8
<0.1 0.6
<0.1 0.76
11.2 21.0 0.2 2.42
0.8
4.01 0.02
<0.002 <0.3 1.95 0.12
8-10
0.1
1.2
0.2
1.08
11.2 29.3 0.2 2.93
0.8
4.03 0.02
<0.002 <0.3 2.97 0.11
The relationship between Al and P in stations is given in Figure 2. The positive relationship between Al and P in
Karakum indicates that P may be of terrestrial origin. P% values higher than those in expected Al from the Inner
Harbor, it can be attributed to the sewer entrances in that area. Figure 3 shows the relationship between Ca and Al
in stations. Bat and Baki (2014) pointed out that Sinop peninsula coasts, affected with intensive land-based
pollution and organic matter discharge originating from domestic wastewater without any treatment. Further,
tourism is also a factor (Baki et al., 2015).
