 
          Biological Evidence 2018, Vol.8, No.3, 21-31
        
        
        
          26
        
        
          Table 2 Level of heavy metals in sediment along Nun River at Gbarantoru and Tombia towns in Bayelsa state, Nigeria
        
        
          Parameters  Around oil and gas
        
        
          installations (Location A)
        
        
          Gbarantoru (Location B) Tombia (Location C)
        
        
          Median mean
        
        
          Geometric mean
        
        
          Cd, mg/kg 0.012±0.000b
        
        
          0.011±0.000b
        
        
          0.005±0.002a
        
        
          0.011
        
        
          0.008
        
        
          Cr, mg/kg
        
        
          0.003±0.001c
        
        
          0.002±0.000b
        
        
          0.001±0.000a
        
        
          0.002
        
        
          0.002
        
        
          Co, mg/kg 0.002±0.000b
        
        
          0.001±0.000a
        
        
          0.001±0.000a
        
        
          0.001
        
        
          0.001
        
        
          Ni, mg/kg 0.032±0.000c
        
        
          0.012±0.000b
        
        
          0.001±0.000a
        
        
          0.012
        
        
          0.008
        
        
          Pb, mg/kg 0.017±0.000c
        
        
          0.013±0.000b
        
        
          0.007±0.000a
        
        
          0.013
        
        
          0.012
        
        
          Zn, mg/kg 0.126±0.001c
        
        
          0.110±0.001b
        
        
          0.082±0.001a
        
        
          0.110
        
        
          0.104
        
        
          Fe, mg/kg 0.314±0.001c
        
        
          0.247±0.001b
        
        
          0.138±0.001a
        
        
          0.247
        
        
          0.220
        
        
          Note: Data is expressed as mean ± standard error (n=3); Different letters across the row indicate significant difference (P<0.05)
        
        
          according to Tukey Honestly Significance difference statistics
        
        
          Table 3 Spearman's rho of the sediment quality studied parameters
        
        
          Parameters
        
        
          Cd
        
        
          Cr
        
        
          Co
        
        
          Ni
        
        
          Pb
        
        
          Zn
        
        
          Fe
        
        
          Cd
        
        
          1.000
        
        
          Cr
        
        
          0.983
        
        
          **
        
        
          1.000
        
        
          Co
        
        
          0.845
        
        
          **
        
        
          0.887
        
        
          **
        
        
          1.000
        
        
          Ni
        
        
          0.933
        
        
          **
        
        
          0.950
        
        
          **
        
        
          0.803
        
        
          **
        
        
          1.000
        
        
          Pb
        
        
          0.917
        
        
          **
        
        
          0.900
        
        
          **
        
        
          0.678
        
        
          *
        
        
          0.950
        
        
          **
        
        
          1.000
        
        
          Zn
        
        
          0.950
        
        
          **
        
        
          0.967
        
        
          **
        
        
          0.837
        
        
          **
        
        
          0.967
        
        
          **
        
        
          0.933
        
        
          **
        
        
          1.000
        
        
          Fe
        
        
          0.867
        
        
          **
        
        
          0.883
        
        
          **
        
        
          0.912
        
        
          **
        
        
          0.883
        
        
          **
        
        
          0.817
        
        
          **
        
        
          0.883
        
        
          **
        
        
          1.000
        
        
          Note: **. Correlation is significant at the 0.01 level (2-tailed); *. Correlation is significant at the 0.05 level (2-tailed); N=9; n=3
        
        
          Lead concentration in the sediment ranged from 0.007-0.017 mg/kg. There was significant variation (P<0.05)
        
        
          among the various locations (Table 2). Lead showed positive significant correlation with zinc (r=0.933) and iron
        
        
          (r=0.817) at P<0.01 (Table 3).
        
        
          Zinc concentration in the sediment ranged from 0.082-0.126 mg/kg. There was significant variation (P<0.05)
        
        
          among the various locations (Table 2). Zinc showed positive significant relationship iron (r=0.883, P<0.01) (Table
        
        
          3). The level of iron in the sediment samples ranged from 0.138-0.314 mg/kg. There was significant variation
        
        
          (P<0.05) among the various locations (Table 2).
        
        
          The sediment showed that there was significant variation (P<0.05) among most of the locations for each of the
        
        
          heavy metals. Furthermore, the results also showed that location A has higher heavy metal concentration
        
        
          compared to Location B and C. This suggests possible human impacts in the areas. Furthermore, all the heavy
        
        
          metals showed positive significant relationship (P<0.05) suggesting that the source of the heavy metals in the
        
        
          sediment is of similar origin. The concentration of the respective heavy metals in sediment had some similarity
        
        
          with the values previously reported in Warri river (Aghoghovwia et al., 2015) and Kolo creek (Ogamba et al.,
        
        
          2017b). This suggests that surface water is a major recipient of anthropogenic activities from both water and land.
        
        
          Typically, surface water has relationship with water quality (Seiyaboh et al., 2016a; 2017c; Kigigha et al., 2018).
        
        
          As such water contaminants tend to sink in the bottom of the water often called sediment. The values of heavy
        
        
          metals of the water quality tend to be lower compared to the sediment heavy metals concentrations. These trends
        
        
          have been reported by Aghoghovwia et al. (2015) on their study on water and sediment quality of Warri River.
        
        
          Table 4 presents contamination factor, degree of contamination and pollution load index of the heavy metals
        
        
          concentration in sediment of Nun River at Gbarantoru and Tombia towns in Bayelsa state, Nigeria. The results
        
        
          showed that heavy metals pollution level ranged from low contamination (CF < 1) to moderate contamination (1 ≤
        
        
          CF <3) for all the heavy metals in the different location under both background scenarios except for Nickel in
        
        
          Location A under geometric mean background scenario. The results also showed that locations A were most
        
        
          contaminated.